Selective Chlorination of Methane Photochemically Mediated by Ferric Chloride at Ambient Temperature

Selective Speciation of Ferric Iron by a New Heterocyclic Ligand

The synthesis and analytical applications of the new heterocyclic ligand are described. The complexation reaction of the ligand with some cations was studied in aqueous methanol at room temperature using the spectrophotometric method. Results revealed that only the absorption spectra of the Fe (III)–ligand complex show a high redshift of the absorption maximum in the aqueous methanol soluti...

Treatment of Highly Turbid Water by Polyaluminum Ferric Chloride (PAFCL)

Background & Aims of the Study: In some situation like rainfall seasons raw water become very turbid so it affected the water treatment plant processes and quality of produced water. Treatment of very high turbid water has some concerns like precursors for disinfection by-products and very loading rate of particle on filter's media and consequently increases in water consumptio...

Selective Oxidation of Glycerol by Highly Active Bimetallic Catalysts at Ambient Temperature under Base-Free Conditions**

Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride.

Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash colum...

Liquid structure of trihexyltetradecylphosphonium chloride at ambient temperature: an X-ray scattering and simulation study.

We report on an experimental and simulation study done on a representative room temperature ionic liquid, namely tetradecyltrihexylphosphonium chloride, at ambient conditions. The study was conducted using small and wide angle X-ray scattering and molecular dynamics simulations. Both approaches converge in indicating that this material is characterized by the existence of strong P-Cl interactio...